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Tetrakis(?-2-chloro-benzoato-?O:O')bis-[(4-vinyl-pyridine-?N)copper(II)].

ABSTRACT: The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol-ecules with a Cu?Cu separation of 2.6676?(12)?Å. In the mol-ecule, four 2-chloro-benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl-pyridine ligands coordinate them in axial positions. The Cu(II) ion has a distorted square-planar pyramidal coordination, with four O atoms from the chlorobenzoate anions at the base. The N pyridine atom completes the coordination environment in the apical position.

SUBMITTER: Zhao J

PROVIDER: S-EPMC2959459 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Tetrakis(μ-2-chloro-benzoato-κO:O')bis-[(4-vinyl-pyridine-κN)copper(II)].

Zhao Juan J

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol-ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol-ecule, four 2-chloro-benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl-pyridine ligands coordinate them in axial positions. The Cu(II) ion has a distorted square-planar pyramidal coordination, with four O atoms from the chlorobenzoate anions at the base. The N pyridine atom completes the coordination environment in the ...[more]

PMID: 21201069

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