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Aqua-bis-[4-(methyl-sulfan-yl)benzoato-?O]bis-(pyridine-?N)copper(II).

ABSTRACT: In the title mol-ecule, [Cu(C(8)H(7)O(2)S)(2)(C(5)H(5)N)(2)(H(2)O)], the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of two 4-(methyl-sulfan-yl)benzoate anions and two N atoms of two pyridine ligands and a water O atom situated at the apical site. In the crystal structure, O-H?O hydrogen bonds link mol-ecules into chains along the b axis.

SUBMITTER: Jiang GQ 

PROVIDER: S-EPMC2983350 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO]bis-(pyridine-κN)copper(II).

Jiang Guo-Qing GQ   Chen Jian-Hua JH   Wang Miao M   Shi Yu-Jun YJ  

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10

In the title mol-ecule, [Cu(C(8)H(7)O(2)S)(2)(C(5)H(5)N)(2)(H(2)O)], the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of two 4-(methyl-sulfan-yl)benzoate anions and two N atoms of two pyridine ligands and a water O atom situated at the apical site. In the crystal structure, O-H⋯O hydrogen bonds link mol-ecules into chains along the b axis. ...[more]

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