Ontology highlight
ABSTRACT:
SUBMITTER: Wang F
PROVIDER: S-EPMC2959584 | biostudies-literature | 2008 Oct
REPOSITORIES: biostudies-literature
Wang Feng F Zhang Jianming J Wang Qirong Q Huang Shiying S
Acta crystallographica. Section E, Structure reports online 20081025 Pt 11
In the title compound, [Mn(C(5)H(6)N(3)O)(2)(C(3)H(7)NO)]ClO(4), the Mn(III) atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octa-hedral coordination geometry, formed by two N atoms and two O atoms from two 1-methyl-imidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethyl-formamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C-H⋯O hydrogen-bonding inter- ...[more]