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Hexakis(N,N-dimethyl-formamide-?O)cobalt(II) bis-(perchlorate).

ABSTRACT: The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H?O hydrogen-bonding inter-actions.

SUBMITTER: Eissmann F

PROVIDER: S-EPMC2983736 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate).

Eissmann Frank F Böhle Tony T Mertens Florian O R L FO Weber Edwin E

Acta crystallographica. Section E, Structure reports online 20100210 Pt 3

The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H⋯O hydrogen-bonding inter-actions. ...[more]

PMID: 21580225

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| S-EPMC2980005 | biostudies-literature

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| S-EPMC3515142 | biostudies-literature

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