Browse
Submit Data
Databases
API
Help

Dataset Information

24 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(E)-Methyl N'-[1-(4-methyl-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

ABSTRACT: The title mol-ecule, C(11)H(14)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 7.61?(16)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H?O hydrogen bonds and the dimers are linked together by C-H?? inter-actions.

SUBMITTER: Lv LP

PROVIDER: S-EPMC2959613 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(E)-Methyl N'-[1-(4-methyl-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Lv Lu-Ping LP Yu Wen-Bo WB Wang Feng F Li Wei-Wei WW Hu Xian-Chao XC

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

The title mol-ecule, C(11)H(14)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 7.61 (16)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H⋯O hydrogen bonds and the dimers are linked together by C-H⋯π inter-actions. ...[more]

PMID: 21580937

Similar Datasets

(E)-Methyl N'-[1-(2-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:The mol-ecule of the title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 8.98?(7)°. Intra-molecular O-H?N and C-H?N hydrogen bonds are observed. Mol-ecules are linked into chains along the c axis by N-H?O hydrogen bonds. In addition, C-H?? inter-actions are observed.

| S-EPMC2960736 | biostudies-literature

Methyl (E)-N'-[1-(2,4-dihydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:The mol-ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the methyl hydrazinecarboxyl-ate plane is 3.01?(6)°. An intra-molecular O-H?N hydrogen bond is observed. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (10) by O-H?O, N-H?O and C-H?O hydrogen bonds.

| S-EPMC2977410 | biostudies-literature

(E)-Methyl N'-[1-(4-methoxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:The mol-ecule of the title compound, C(11)H(14)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 12.06?(9)°. Mol-ecules are linked into a one-dimensional network by N-H?O hydrogen bonds and C-H?? inter-actions. The benzene rings of inversion-related mol-ecules are stacked with their centroids separated by 3.777?(1)?Å, indicating ?-? inter-actions.

| S-EPMC2960734 | biostudies-literature

(E)-Methyl N'-[1-(4-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:The title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazine carboxylic acid plane is 8.29 (7)°. Mol-ecules are linked into a three-dimensional network by N-H⋯O, O-H⋯O, O-H⋯N hydrogen bonds and C-H⋯π inter-actions.

| S-EPMC2960493 | biostudies-literature

(E)-Ethyl N'-[1-(2-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:In the mol-ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl-ate mean plane is 3.65 (12)°. Intra-molecular C-H⋯N and O-H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, inter-molecular N-H⋯O and C-H⋯N hydrogen bonds link the mol-ecules. There is a C-H⋯π contact between the benzene ring and the methyl group of the ethyl substituent.

| S-EPMC2960505 | biostudies-literature

(E)-Ethyl N'-[1-(4-methoxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:The mol-ecule of the title compound, C(12)H(16)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 13.82 (6)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H⋯O and C-H⋯O hydrogen bonds, and the dimers are linked together by C-H⋯π inter-actions.

| S-EPMC2959676 | biostudies-literature

Methyl N'-[(E)-1-phenyl-ethyl-idene]hydrazinecarboxyl-ate.

Project description:The mol-ecule of the title compound, C(10)H(12)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the phenyl ring and the hydrazine carboxylic acid mean plane is 25.23 (9)°. In the crystal structure, mol-ecules are linked into chains by N-H⋯O hydrogen bonds and C-H⋯π inter-actions.

| S-EPMC2962017 | biostudies-literature

(E)-Methyl N'-[(1H-indol-3-yl)methyl-idene]hydrazinecarboxyl-ate 0.25-hydrate.

Project description:The asymmetric unit of the title compound, C(11)H(11)N(3)O(2)·0.25H(2)O, contains two independent organic mol-ecules and a water mol-ecule, which lies on a twofold rotation axis. The side chains of the two mol-ecules have slightly different orientations, the C=N-N-C torsion angle being -163.03 (15)° in one and -177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, mol-ecules are linked into chains extending along b by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds and in addition, four inter-molecular C-H⋯π inter-actions are present.

| S-EPMC3212339 | biostudies-literature

(E)-Ethyl N'-(3,4,5-trimethoxy-benzyl-idene)hydrazinecarboxyl-ate.

Project description:The mol-ecule of the title compound, C(13)H(18)N(2)O(5), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 49.75 (5)° and an intra-molecular C-H⋯O inter-action occurs. In the crystal structure, the mol-ecules are linked into a chain along [010] by N-H⋯O hydrogen bonds, and a C-H⋯π contact further stabilizes the structure.

| S-EPMC2959716 | biostudies-literature

(E)-Ethyl N'-(2-hydroxy-benzyl-idene)-hydrazinecarboxyl-ate.

Project description:There are two mol-ecules in the asymmetric unit of the title compound, C(10)H(12)N(2)O(3), with identical conformations. Each independent mol-ecule is approximately planar and adopts a trans configuration with respect to the C=N double bond. Intra-molecular O-H⋯N hydrogen bonds are observed in both mol-ecules. The mol-ecules are linked into a ribbon-like structure running along the b axis by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds. The ribbons are arranged into layers parallel to (02).

| S-EPMC2962171 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data