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(E)-Ethyl N'-(3,4,5-trimethoxy-benzyl-idene)hydrazinecarboxyl-ate.

ABSTRACT: The mol-ecule of the title compound, C(13)H(18)N(2)O(5), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 49.75?(5)° and an intra-molecular C-H?O inter-action occurs. In the crystal structure, the mol-ecules are linked into a chain along [010] by N-H?O hydrogen bonds, and a C-H?? contact further stabilizes the structure.

SUBMITTER: Lv LP 

PROVIDER: S-EPMC2959716 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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(E)-Ethyl N'-(3,4,5-trimethoxy-benzyl-idene)hydrazinecarboxyl-ate.

Lv Lu-Ping LP   Ding Xiao-Ming XM   Yu Wen-Bo WB   Li Wei-Wei WW   Hu Xian-Chao XC  

Acta crystallographica. Section E, Structure reports online 20081018 Pt 11

The mol-ecule of the title compound, C(13)H(18)N(2)O(5), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 49.75 (5)° and an intra-molecular C-H⋯O inter-action occurs. In the crystal structure, the mol-ecules are linked into a chain along [010] by N-H⋯O hydrogen bonds, and a C-H⋯π contact further stabilizes the structure. ...[more]

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