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Bis(4,4'-methyl-enedicyclo-hexyl-aminium) ?-benzene-1,4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate.

ABSTRACT: The title compound, (C(13)H(28)N(2))(2)[Zn(2)(C(8)H(4)O(4))Cl(6)]·4H(2)O, was prepared by the reaction of ZnCl(2)·6H(2)O, benzene-1,4-dicarboxylic acid and 4,4'-diamino-dicyclo-hexyl-methane in methanol. The [Zn(2)Cl(6)(C(8)H(4)O(4))](4-) anions lie on centres of inversion and comprise two ZnCl(3) groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N-H?Cl and N-H?O hydrogen bonds between the cations and anions, solvent water mol-ecules form O-H?O and O-H?Cl hydrogen bonds to give a three-dimensional network.

SUBMITTER: Hsu CY

PROVIDER: S-EPMC2959686 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis(4,4'-methyl-enedicyclo-hexyl-aminium) μ-benzene-1,4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate.

Hsu Chen-Yen CY Yeh Chun-Wei CW Wu Chi-Phi CP Lin Chia-Her CH Chen Jhy-Der JD

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11

The title compound, (C(13)H(28)N(2))(2)[Zn(2)(C(8)H(4)O(4))Cl(6)]·4H(2)O, was prepared by the reaction of ZnCl(2)·6H(2)O, benzene-1,4-dicarboxylic acid and 4,4'-diamino-dicyclo-hexyl-methane in methanol. The [Zn(2)Cl(6)(C(8)H(4)O(4))](4-) anions lie on centres of inversion and comprise two ZnCl(3) groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N-H⋯Cl and N-H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O-H⋯O and O-H⋯Cl hydrogen bonds to give a thre ...[more]

PMID: 21580861

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Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato)nickelate(II) penta-hydrate.

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| S-EPMC3998499 | biostudies-literature

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