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Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato)nickelate(II) penta-hydrate.

ABSTRACT: In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral fashion. The crystal packing is stabilized by inter-molecular O-H?O and N-H?O and weak C-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distances = 3.4669?(19) and 3.764?(2)?Å].

SUBMITTER: Pasdar H 

PROVIDER: S-EPMC3051631 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato)nickelate(II) penta-hydrate.

Pasdar Hoda H   Sadat Kashani Saghi S   Aghabozorg Hossein H   Notash Behrouz B  

Acta crystallographica. Section E, Structure reports online 20110115 Pt 2

In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral fashion. The crystal packing is stabilized by inter-molecular O-H⋯O and N-H⋯O and weak C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distances = 3.4669 (19) and 3.764 (2) Å]. ...[more]

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