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(E)-Ethyl N'-(3-hy-droxy-benzyl-idene)hydrazinecarboxyl-ate dihydrate.

ABSTRACT: The asymmetric unit of the title compound, C(10)H(12)N(2)O(3)·2H(2)O, contains two organic mol-ecules with similar conformations and four water mol-ecules. Each organic mol-ecule is close to planar (r.m.s. deviations = 0.035 and 0.108?Å) and adopts a trans conformation with respect to its C=N bond. In the crystal, the components are linked into a three-dimensional network by N-H?O, O-H?O, O-H?N and C-H?O hydrogen bonds, some of which are bifurcated. An R(2) (2)(8) loop occurs between adjacent organic mol-ecules.

SUBMITTER: Hu XC

PROVIDER: S-EPMC3212279 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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(E)-Ethyl N'-(3-hy-droxy-benzyl-idene)hydrazinecarboxyl-ate dihydrate.

Hu Xian-Chao XC Zhang Jie J Yang Da-Yong DY Lv Lu-Ping LP

Acta crystallographica. Section E, Structure reports online 20110702 Pt 8

The asymmetric unit of the title compound, C(10)H(12)N(2)O(3)·2H(2)O, contains two organic mol-ecules with similar conformations and four water mol-ecules. Each organic mol-ecule is close to planar (r.m.s. deviations = 0.035 and 0.108 Å) and adopts a trans conformation with respect to its C=N bond. In the crystal, the components are linked into a three-dimensional network by N-H⋯O, O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, some of which are bifurcated. An R(2) (2)(8) loop occurs between adjacent or ...[more]

PMID: 22090936

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