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Bis[4-(2-nitro-benzene-sulfonamido)-pyridinium] hexa-fluoro-silicate.

ABSTRACT: In the title compound, 2C(11)H(10)N(3)O(4)S(+)·SiF(6) (2-), the short C-N distance [1.386 (2) Å] is indicative of a slight conjugation of N with the π electrons of the pyridinium ring, and with those of the sulfonyl group. The dihedral angle between the benzene and pyridinium rings is 77.48 (7)°. The crystal structure is stabilized by N-H⋯F and C-H⋯F hydrogen bonds. The Si atom of the anion lies on a special position.

SUBMITTER: Wang AR

PROVIDER: S-EPMC2959800 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Bis[4-(2-nitro-benzene-sulfonamido)-pyridinium] hexa-fluoro-silicate.

Wang Ai-Rong AR

Acta crystallographica. Section E, Structure reports online 20081122 Pt 12

In the title compound, 2C(11)H(10)N(3)O(4)S(+)·SiF(6) (2-), the short C-N distance [1.386 (2) Å] is indicative of a slight conjugation of N with the π electrons of the pyridinium ring, and with those of the sulfonyl group. The dihedral angle between the benzene and pyridinium rings is 77.48 (7)°. The crystal structure is stabilized by N-H⋯F and C-H⋯F hydrogen bonds. The Si atom of the anion lies on a special position. ...[more]

PMID: 21581374

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