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2-(Benzene-sulfonamido)pyridinium perchlorate.


ABSTRACT: In the title compound, C(11)H(11)N(2)O(2)S(+)·ClO(4) (-), the dihedral angle between the benzene and pyridinium rings is 87.33?(10)°. An intra-molecular N-H?O inter-action, with an S=O-bonded O atom as receptor, occurs in the cation. In the crystal structure, ion pairs occur, being linked by strong N-H?O hydrogen bonds. The perchlorate anion plays a further role in the mol-ecular packing by accepting several weak C-H?O inter-actions.

SUBMITTER: Li X 

PROVIDER: S-EPMC2969619 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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2-(Benzene-sulfonamido)pyridinium perchlorate.

Li Xun X   Xie Dan D   Xiao Zhi-Hong ZH   Li Chang-Zhu CZ  

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6


In the title compound, C(11)H(11)N(2)O(2)S(+)·ClO(4) (-), the dihedral angle between the benzene and pyridinium rings is 87.33 (10)°. An intra-molecular N-H⋯O inter-action, with an S=O-bonded O atom as receptor, occurs in the cation. In the crystal structure, ion pairs occur, being linked by strong N-H⋯O hydrogen bonds. The perchlorate anion plays a further role in the mol-ecular packing by accepting several weak C-H⋯O inter-actions. ...[more]

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