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Tert-Butyl N-(5-bromo-1H-imidazo[4,5-b]pyridin-2-ylmeth-yl)carbamate.

ABSTRACT: In the mol-ecule of the title compound, C(12)H(15)BrN(4)O(2), the imidazole and pyridine rings are strictly coplanar [maximum deviation 0.006?(3)?Å]. In the crystal structure, mol-ecules are linked into chains running parallel to the a axis by inter-molecular N-H?O hydrogen bonds. Centrosymmetrically related chains are further connected by N-H?N hydrogen-bonding inter-actions to form a two-dimensional layer structure parallel to the ab plane.

SUBMITTER: Yin L

PROVIDER: S-EPMC2959901 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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tert-Butyl N-(5-bromo-1H-imidazo[4,5-b]pyridin-2-ylmeth-yl)carbamate.

Yin Ling L Jia Jiong J Zhao Gui-Long GL Wang Jian-Wu JW

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

In the mol-ecule of the title compound, C(12)H(15)BrN(4)O(2), the imidazole and pyridine rings are strictly coplanar [maximum deviation 0.006 (3) Å]. In the crystal structure, mol-ecules are linked into chains running parallel to the a axis by inter-molecular N-H⋯O hydrogen bonds. Centrosymmetrically related chains are further connected by N-H⋯N hydrogen-bonding inter-actions to form a two-dimensional layer structure parallel to the ab plane. ...[more]

PMID: 21581243

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