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Bis{2-[(2-cyano-phen-yl)imino-meth-yl]phenolato}copper(II).

ABSTRACT: In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu-N and Cu-O bond lengths are 2.009?(2) and 1.888?(2)?Å, respectively. The dihedral angle between the cyano-phenyl rings and phenolate rings is 42.28?(13)°.

SUBMITTER: Xia R

PROVIDER: S-EPMC2959947 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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Bis{2-[(2-cyano-phen-yl)imino-meth-yl]phenolato}copper(II).

Xia Rong R Xu Hai-Jun HJ Wang Han H

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu-N and Cu-O bond lengths are 2.009 (2) and 1.888 (2) Å, respectively. The dihedral angle between the cyano-phenyl rings and phenolate rings is 42.28 (13)°. ...[more]

PMID: 21581153

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