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Bis{2-meth-oxy-6-[(3-pyrid-yl)methyl-imino-meth-yl]phenolato}copper(II).

ABSTRACT: In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61?(5)°. Intra-molecular C-H?O hydrogen bonds are present. The crystal structure is stabilized by weak aromatic ?-? stacking inter-actions involving neighbouring pyridine rings [centroid-centroid distance = 3.853?(2)?Å].

SUBMITTER: Wang Y

PROVIDER: S-EPMC2970154 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Bis{2-meth-oxy-6-[(3-pyrid-yl)methyl-imino-meth-yl]phenolato}copper(II).

Wang Yun Y Zhu Li-Li LL Sun Bai-Wang BW

Acta crystallographica. Section E, Structure reports online 20090812 Pt 9

In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61 (5)°. Intra-molecular C-H⋯O hydrogen bonds are present. The crystal structure is stabilized by weak aromatic π-π stacking inter-actions involving neighbouring pyridine rings [centroid-centroid distance = 3.853 (2) Å]. ...[more]

PMID: 21577417

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Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).

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Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

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