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2-(4-Ferrocenylphen-yl)-4,4,5,5-tetra-methyl-1,3,2-dioxaborolane.

ABSTRACT: In the title compound,, [Fe(C(5)H(5))(C(17)H(20)BO(2))], the two near parallel cyclo-penta-dienyl rings of the ferrocene group are eclipsed. The benzene ring is tilted with respect to the attached cyclo-penta-diene ring by 17.0 (1)° and by 24.2 (1)° with respect to the dioxaborolane ring. The mol-ecules assemble in the crystal via C-H⋯π inter-actions between the cyclo-penta-dienyl H atoms and the benzene and cyclo-penta-dienyl rings of neighbouring mol-ecules.

SUBMITTER: Boyd PD

PROVIDER: S-EPMC2959994 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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2-(4-Ferrocenylphen-yl)-4,4,5,5-tetra-methyl-1,3,2-dioxaborolane.

Boyd Peter D W PD Paauwe J D JD

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

In the title compound,, [Fe(C(5)H(5))(C(17)H(20)BO(2))], the two near parallel cyclo-penta-dienyl rings of the ferrocene group are eclipsed. The benzene ring is tilted with respect to the attached cyclo-penta-diene ring by 17.0 (1)° and by 24.2 (1)° with respect to the dioxaborolane ring. The mol-ecules assemble in the crystal via C-H⋯π inter-actions between the cyclo-penta-dienyl H atoms and the benzene and cyclo-penta-dienyl rings of neighbouring mol-ecules. ...[more]

PMID: 21581115

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