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An inter-molecular dative B?N bond in 5-(4,4,5,5-tetra-methyl-1,3,2-dioxa-borolan-2-yl)-1,3-thia-zole.


ABSTRACT: The title compound, C(9)H(14)BNO(2)S, is in an unusual bend conformation and the B atom of one mol-ecule within the crystal forms an inter-molecular dative bond with the N atom of a neighbouring mol-ecule, an infrequent phenomenon in boronic derivative crystals.

SUBMITTER: Sopkova-de Oliveira Santos J 

PROVIDER: S-EPMC2980002 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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An inter-molecular dative B←N bond in 5-(4,4,5,5-tetra-methyl-1,3,2-dioxa-borolan-2-yl)-1,3-thia-zole.

Sopková-de Oliveira Santos Jana J   Primas Nicolas N   Lohier Jean-François JF   Bouillon Alexandre A   Rault Sylvain S  

Acta crystallographica. Section E, Structure reports online 20091216 Pt 1


The title compound, C(9)H(14)BNO(2)S, is in an unusual bend conformation and the B atom of one mol-ecule within the crystal forms an inter-molecular dative bond with the N atom of a neighbouring mol-ecule, an infrequent phenomenon in boronic derivative crystals. ...[more]

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