Browse
Submit Data
Databases
API
Help

Dataset Information

31 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(5-Bromo-2-hydroxy-phen-yl)(phen-yl)methanone.

ABSTRACT: In the title compound, C(13)H(9)BrO(2), the dihedral angle between the aromatic ring planes is 53.6?(1)°. The crystal structure is stabilized by intra-molecular O-H?O and inter-molecular C-H?O hydrogen bonding and C-H?? inter-actions.

SUBMITTER: Zheng CZ

PROVIDER: S-EPMC2960004 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(5-Bromo-2-hydroxy-phen-yl)(phen-yl)methanone.

Zheng Chang-Zheng CZ Ji Chang-You CY Chang Xiu-Li XL Zhang Li-Qin LQ

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12

In the title compound, C(13)H(9)BrO(2), the dihedral angle between the aromatic ring planes is 53.6 (1)°. The crystal structure is stabilized by intra-molecular O-H⋯O and inter-molecular C-H⋯O hydrogen bonding and C-H⋯π inter-actions. ...[more]

PMID: 21581450

Similar Datasets

(5-Bromo-2-hydroxy-phen-yl)(phen-yl)methanone.

Project description:In the title compound, C(13)H(9)BrO(2), the mol-ecular conformation is stabilized by an intra-molecular O-H?O hydrogen bond. In the crystal structure, weak inter-molecular C-H?O hydrogen-bonding inter-actions link the mol-ecules into chains along the c-axis direction.

| S-EPMC2959262 | biostudies-literature

(5-Bromo-2-chloro-phen-yl)(4-ethoxy-phen-yl)methanone.

Project description:In the title mol-ecule, C(15)H(12)BrClO(2), the two benzene rings form a dihedral angle of 69.30 (3)°. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules into chains propagating along the b axis.

| S-EPMC2971929 | biostudies-literature

(4-Bromo-phen-yl)(1H-indol-7-yl)methanone.

Project description:In the crystal, the mol-ecules of the title compound, C(15)H(10)BrNO, are connected into centrosymmetric dimers by pairs of N-H?O hydrogen bonds. The dihedral angle between the planes of indole ring system and benzene ring is 50.13?(5)°. The indole plane is significantly less twisted from the plane of the central C-C(=O)-C bridge than the benzene plane [dihedral angles = 15.51?(3) and 40.13?(7)°, respectively]. The bond angles within the benzene ring show an approximately additive effect of the influence of both substituents.

| S-EPMC2971073 | biostudies-literature

(5-Bromo-2-methyl-phen-yl)(4-eth-oxy-phen-yl)methanone.

Project description:In the title compound, C(16)H(15)BrO(2), the dihedral angle between the benzene rings is 68.5?(2)°. In the crystal structure, mol-ecules are linked by weak C-H?O hydrogen bonds into chains parallel to the b axis.

| S-EPMC3007335 | biostudies-literature

{2-[(3-Bromo-benzyl-idene)amino]-5-chloro-phen-yl}(phen-yl)methanone.

Project description:In the title compound, C(20)H(13)BrClNO, the azomethine double bond [C=N = 1.246?(4)?Å] adopts an E conformation. The bromo- and chlorophenyl rings are inclined to one another by 13.70?(11)°, and form dihedral angles of 76.68?(10) and 74.24?(7)°, respectively, with the phenyl ring. In the crystal, mol-ecules are linked by C-H?O hydrogen bonds to form double stranded chains propagating along the b-axis direction.

| S-EPMC3295437 | biostudies-literature

(4-Bromo-phen-yl)(2,7-dimeth-oxy-1-naphth-yl)methanone.

Project description:In the title compound, C(19)H(15)BrO(3), the dihedral angle between the naphthalene ring system and the benzene ring is 72.02?(9)°. The bridging carbonyl C-C(=O)-C plane makes dihedral angles of 70.88?(10) and 1.87?(12)°, respectively, with the naphthalene ring system and the benzene ring. In the crystal, two types of weak inter-molecular C-H?O inter-actions and a short Br?C contact [3.345?(2)?Å] are observed.

| S-EPMC3009358 | biostudies-literature

{2-[(1,3-Benzo-thia-zol-2-yl)meth-oxy]-5-bromo-phen-yl}(phen-yl)methanone.

Project description:In the title compound, C21H14BrNO2S, the dihedral angle between the planes of the benzo-thia-zole and phenyl-methanone groups is 63.4?(2)°. In the crystal, pairs of C-H?N hydrogen bonds link the mol-ecules to form inversion dimers, which are further linked by C-H?O inter-actions into chains along the c axis. C-H?? and ?-? inter-actions [centroid-centroid distance = 3.863?(1)?Å] further stabilize the mol-ecular assembly.

| S-EPMC3685117 | biostudies-literature

(4-Bromo-phen-yl)(1-phenyl-sulfonyl-1H-indol-2-yl)methanone.

Project description:In the title compound, C(21)H(14)BrNO(3)S, the indole ring system forms dihedral angles of 65.64?(8) and 59.30?(8)°, respectively, with the phenyl and bromo-phenyl rings. In the crystal, mol-ecules are connected by a C-H?O hydrogen bond, forming a chain along [101]. The chains are further connected by weak inter-molecular C-H?? inter-actions, forming a layer parallel to the ac plane.

| S-EPMC3009294 | biostudies-literature

(5-Bromo-2-hy-droxy-phen-yl)(4-propyl-cyclo-hex-yl)methanone.

Project description:In the title compound, C(16)H(21)BrO(2), the cyclo-hexane ring adopts a chair conformation. The hy-droxy and carbonyl groups are involved in an intra-molecular O-H?O hydrogen bond. In the crystal, weak C-H?O inter-actions link the mol-ecules into zigzag chains along [010].

| S-EPMC3344119 | biostudies-literature

(5-Bromo-2-meth-oxy-phen-yl)(4-ethyl-cyclo-hex-yl)methanone.

Project description:In the title compound, C(16)H(21)BrO(2), the cyclo-hexane ring is in a chair conformation and its least-squares plane is at an angle of 61.3?(9)° to the benzene ring. The crystal packing is stabilized by weak ?-? stacking inter-actions [centroid-centroid distance = 3.697?(9)?Å] between the bromo-meth-oxy-phenyl rings of neighbouring mol-ecules.

| S-EPMC3089268 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data