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Oxonium ammonio-(cyclo-prop-yl)methyl-enebis(hydrogenphospho-nate) monohydrate.

ABSTRACT: The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (-)·H(2)O, was obtained from the reaction of cyclo-propane-carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phospho-nic acid residues and a water mol-ecule of crystallization. The hydroxonium cation and water mol-ecule are hydrogen bonded to the anion and further N-H?O and O-H?O bonds create a three-dimensional network.

SUBMITTER: Bon VV

PROVIDER: S-EPMC2960100 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Oxonium ammonio-(cyclo-prop-yl)methyl-enebis(hydrogenphospho-nate) monohydrate.

Bon V V VV Dudko A V AV Kozachkova A N AN Pekhnyo V I VI

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (-)·H(2)O, was obtained from the reaction of cyclo-propane-carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phospho-nic acid residues and a water mol-ecule of crystallization. The hydroxonium cation and water mol-ecule are hydrogen bonded to the anion and further N-H⋯O and O-H⋯O bonds c ...[more]

PMID: 21581319

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