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{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate.


ABSTRACT: In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral. The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H?O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings. Neighbouring sheets are connected by C-H?O inter-actions.

SUBMITTER: Strasser CE 

PROVIDER: S-EPMC2983634 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate.

Strasser Christoph E CE   Sumani Jimmy E Y JE   Raubenheimer Helgard G HG   Luckay Robert C RC  

Acta crystallographica. Section E, Structure reports online 20100224 Pt 3


In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral. The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H⋯O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings. Neighbouring sheets are connected by C-H⋯O inter-actions. ...[more]

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