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Sodium 2-iodo-benzene-sulfonate monohydrate.

ABSTRACT: In the title compound, Na(+)·C(6)H(4)IO(3)S(-)·H(2)O, the Na atom is hexa-coordinated by O atoms, forming a two-dimensional sheet-like structure in the bc plane, with the iodo-benzene rings protruding above and below. Na?O contact distances are in the range 2.419?(2)-2.7218?(18)?Å and O?Na?O angles are in the range 73.70?(5)-158.64?(7)°. The crystal structure is stabilized by O-H?O and C-H?O hydrogen bonds and C-H?? inter-actions. The I atom is disordered over two positions with occupancies of 0.78?(2) and 0.22?(2).

SUBMITTER: Arshad MN

PROVIDER: S-EPMC2960107 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Sodium 2-iodo-benzene-sulfonate monohydrate.

Arshad Muhammad Nadeem MN Tahir M Nawaz MN Khan Islam Ullah IU Shafiq Muhammad M Siddiqui Waseeq Ahmad WA

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12

In the title compound, Na(+)·C(6)H(4)IO(3)S(-)·H(2)O, the Na atom is hexa-coordinated by O atoms, forming a two-dimensional sheet-like structure in the bc plane, with the iodo-benzene rings protruding above and below. Na⋯O contact distances are in the range 2.419 (2)-2.7218 (18) Å and O⋯Na⋯O angles are in the range 73.70 (5)-158.64 (7)°. The crystal structure is stabilized by O-H⋯O and C-H⋯O hydrogen bonds and C-H⋯π inter-actions. The I atom is disordered over two positions with occupancies of 0 ...[more]

PMID: 21581218

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