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Sodium (1R)-d-glucit-1-yl-sulfonate monohydrate.

ABSTRACT: The title salt, Na(+)·C(6)H(13)O(9)S(-)·H(2)O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of d-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive inter-molecular hydrogen bonding. Each of the independent mol-ecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001 ?). Carbohydr. Res.335, 1-10], but there are significant differences in the patterns of complexation.

SUBMITTER: Haines AH

PROVIDER: S-EPMC3343795 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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Sodium (1R)-d-glucit-1-yl-sulfonate monohydrate.

Haines Alan H AH Hughes David L DL

Acta crystallographica. Section E, Structure reports online 20120307 Pt 4

The title salt, Na(+)·C(6)H(13)O(9)S(-)·H(2)O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of d-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive inter-molecular hydrogen bonding. Each of the independent mol-ecules has an open-chain structure with the carbon chains adopting a sickle- ...[more]

PMID: 22589769

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