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A bi-TTF with a bipyridine spacer: 4,4'-bis-[(3,6,7-trimethyl-sulfanyltetra-thia-fulvalen-2-yl)sulfanylmeth-yl]-2,2'-bipyridine.

ABSTRACT: The title compound, C(30)H(28)N(2)S(16), is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S?S hinges, the dihedral angles being 17.14?(8) and 13.46?(7)°. There is a short S?S contact [3.4863? (14)?Å] in the crystal structure.

SUBMITTER: Kaboub L 

PROVIDER: S-EPMC2960116 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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A bi-TTF with a bipyridine spacer: 4,4'-bis-[(3,6,7-trimethyl-sulfanyltetra-thia-fulvalen-2-yl)sulfanylmeth-yl]-2,2'-bipyridine.

Kaboub Lakhemici L   Fabre Jean-Marc JM   Legros Jean-Pierre JP  

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12

The title compound, C(30)H(28)N(2)S(16), is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)°. There is a short S⋯S contact [3.4863  (14) Å] in the crystal structure. ...[more]

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