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2-[Bis(5-chloro-2-pyridylamino)methyl]pyridine monohydrate.

ABSTRACT: In the title compound, the dihedral angles between the 2-amino-5-chloro-pyridyl rings and the pyridine ring are 56.26?(6)° and 78.83?(5)°; the angle between the 2-amino-5-chloro-pyridyl rings is 72.42?(5)°. The solvent water mol-ecules are linked to the organic compound by N-H?O, O-H?O, N-H?N and O-H?N hydrogen bonds. ??? Stacking inter-actions are also observed between the 2-amino-5-chloro-pyridyl rings (centroid?centroid distance = 3.243?Å).

SUBMITTER: M Boghaei D

PROVIDER: S-EPMC2960150 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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2-[Bis(5-chloro-2-pyridylamino)methyl]pyridine monohydrate.

M Boghaei Davar D Najafpour Mohammad Mahdi MM McKee Vickie V McKee Vickie V

Acta crystallographica. Section E, Structure reports online 20081122 Pt 12

In the title compound, the dihedral angles between the 2-amino-5-chloro-pyridyl rings and the pyridine ring are 56.26 (6)° and 78.83 (5)°; the angle between the 2-amino-5-chloro-pyridyl rings is 72.42 (5)°. The solvent water mol-ecules are linked to the organic compound by N-H⋯O, O-H⋯O, N-H⋯N and O-H⋯N hydrogen bonds. π⋯π Stacking inter-actions are also observed between the 2-amino-5-chloro-pyridyl rings (centroid⋯centroid distance = 3.243 Å). ...[more]

PMID: 21581396

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