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2-[1-(Methyl-sulfan-yl)naphtho[2,1-b]furan-2-yl]acetic acid.

ABSTRACT: The title compound, C(15)H(12)O(3)S, was prepared by alkaline hydrolysis of ethyl 2-{1-(methyl-sulfan-yl)naphtho[2,1-b]furan-2-yl}acetate. The crystal structure is stabilized by CH(2)-H?? inter-actions between the methyl H atoms of the methyl-sulfanyl substituent and the central benzene ring of the naphthofuran system, and by inversion-related inter-molecular O-H?O hydrogen bonds between the carboxyl groups.

SUBMITTER: Choi HD

PROVIDER: S-EPMC2960208 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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2-[1-(Methyl-sulfan-yl)naphtho[2,1-b]furan-2-yl]acetic acid.

Choi Hong Dae HD Seo Pil Ja PJ Son Byeng Wha BW Lee Uk U

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

The title compound, C(15)H(12)O(3)S, was prepared by alkaline hydrolysis of ethyl 2-{1-(methyl-sulfan-yl)naphtho[2,1-b]furan-2-yl}acetate. The crystal structure is stabilized by CH(2)-H⋯π inter-actions between the methyl H atoms of the methyl-sulfanyl substituent and the central benzene ring of the naphthofuran system, and by inversion-related inter-molecular O-H⋯O hydrogen bonds between the carboxyl groups. ...[more]

PMID: 21201480

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