Unknown

Dataset Information

0

Catena-Poly[[[trans-diaqua-bis(pyridine-?N)cobalt(II)]-?-(4-{N'-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethyl-idene]hydrazino}benzoato-?O:N,N')-[bis-(pyridine-?N)cobalt(III)]-?-(4-{N'-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethyl-idene]hydrazino}benzoato-?N,N':O)]perchlorate 3.66-hydrate].

ABSTRACT: The title compound, {[Co(2)(C(15)H(14)N(4)O(3))(2)(C(5)H(5)N)(4)(H(2)O)(2)]ClO(4)·3.66H(2)O}(n), is a one-dimensional coordination polymer, with both Co(II) and Co(III) centres in its structure. The ligand environment surrounding Co(III) is formed by two N,N-chelating pyrazole-containing ligands and two pyridine mol-ecules in axial positions. The high-spin Co(II) ions, situated at crystallographic centres of inversion, exhibit a distorted octa-hedral coordination mode. The ClO(4) (-) anion is linked to the polymer chain via hydrogen bonds. The chains are connected by hydrogen bonds to produce a three-dimensional structure.

SUBMITTER: Penkova L 

PROVIDER: S-EPMC2960270 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[trans-diaqua-bis(pyridine-κN)cobalt(II)]-μ-(4-{N'-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethyl-idene]hydrazino}benzoato-κO:N,N')-[bis-(pyridine-κN)cobalt(III)]-μ-(4-{N'-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethyl-idene]hydrazino}benzoato-κN,N':O)]perchlorate 3.66-hydrate].

Penkova Larysa L   Azarkh Mikhail P MP   Haukka Matti M   Meyer Franc F   Fritsky Igor O IO  

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2

The title compound, {[Co(2)(C(15)H(14)N(4)O(3))(2)(C(5)H(5)N)(4)(H(2)O)(2)]ClO(4)·3.66H(2)O}(n), is a one-dimensional coordination polymer, with both Co(II) and Co(III) centres in its structure. The ligand environment surrounding Co(III) is formed by two N,N-chelating pyrazole-containing ligands and two pyridine mol-ecules in axial positions. The high-spin Co(II) ions, situated at crystallographic centres of inversion, exhibit a distorted octa-hedral coordination mode. The ClO(4) (-) anion is li  ...[more]

Similar Datasets

Unknown Bis(2-amino-pyridine-κN)bis-(benzoato-κO)cobalt(II).
| S-EPMC2947776 | biostudies-literature
Unknown catena-Poly[[aqua-{4-[N'-(2,4-dioxo-3-pentyl-idene)-hydrazino]-benzoato}-copper(II)]-μ-acetato].
| S-EPMC2961769 | biostudies-literature
Unknown Tetrakis(μ-2-chloro-benzoato-κO:O')bis-[(4-vinyl-pyridine-κN)copper(II)].
| S-EPMC2959459 | biostudies-literature
Unknown Diaqua-bis-(N,N-diethyl-nicotinamide-κN)bis-(4-ethyl-benzoato-κO)cobalt(II).
| S-EPMC3089307 | biostudies-literature
Unknown catena-Poly[[[2,6-bis-(pyrazol-1-yl-κN)pyridine-κN](nitrato-κO,O')cadmium(II)]-μ-thio-cyanato-κN:S].
| S-EPMC2959772 | biostudies-literature
Unknown Chloridobis(dimethyl-glyoximato-κN,N')(ethyl pyridine-4-carboxyl-ate-κN)cobalt(III) chloro-form monosolvate.
| S-EPMC3274923 | biostudies-literature
Unknown Aqua-bis-(4-chloro-benzoato)-κ(2) O,O';κO-bis-(pyridine-κN)cobalt(II).
| S-EPMC3629487 | biostudies-literature
Unknown Tetra-kis-(μ-benzoato-κO:O')bis{[4-(di-methyl-amino)-pyridine-κN]zinc(II)}.
| S-EPMC3051476 | biostudies-literature
Unknown [N'-(3-Meth-oxy-2-oxidobenzyl-idene-κO)benzohydrazidato-κN',O]tris-(pyridine-κN)cobalt(III) perchlorate.
| S-EPMC3051920 | biostudies-literature
Unknown Di-μ-azido-bis-({N'-[1-(2-pyrid-yl-κN)ethyl-idene]acetohydrazidato-κN',O}dicopper(II)).
| S-EPMC2983124 | biostudies-literature