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(E)-1-Ferrocenyl-3-(4-methoxy-phen-yl)-prop-2-en-1-one.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], a conjugated substituent group bridges a five-membered ?(5)-C(5)H(4) ring and a benzene ring. In the ferrocene unit, the substituted (Cps) and unsubstituted (Cp) cyclo-penta-dienyl rings are eclipsed and almost parallel [Cps-Fe-Cps angle = 176.1?(2)°]. The mol-ecule is linked into an S(5) motif via intra-molecular C-H?O hydrogen bonds. The mol-ecules are arranged into a three-dimensional framework by five inter-molecular C-H?O hydrogen bonds and one inter-molecular C-H??(Cps) inter-action.

SUBMITTER: Long SJ

PROVIDER: S-EPMC2960594 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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(E)-1-Ferrocenyl-3-(4-methoxy-phen-yl)-prop-2-en-1-one.

Long Shi-Jia SJ Liu Xiao-Lan XL Liu Yong-Hong YH

Acta crystallographica. Section E, Structure reports online 20080813 Pt 9

In the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], a conjugated substituent group bridges a five-membered η(5)-C(5)H(4) ring and a benzene ring. In the ferrocene unit, the substituted (Cps) and unsubstituted (Cp) cyclo-penta-dienyl rings are eclipsed and almost parallel [Cps-Fe-Cps angle = 176.1 (2)°]. The mol-ecule is linked into an S(5) motif via intra-molecular C-H⋯O hydrogen bonds. The mol-ecules are arranged into a three-dimensional framework by five inter-molecular C-H⋯O hydrogen bonds ...[more]

PMID: 21201612

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