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Bis(diphenyl-phospho-rothio-yl) tris-ulfide.

ABSTRACT: In the title compound, C(24)H(20)P(2)S(5), the P atoms are arranged trans with respect to the S(3) group and the S=P-S-S systems have cisoid geometry, with an average S-P-S-S torsion angle of -56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33?(12) and 75.67?(10)°. In the crystal structure, the mol-ecules are linked into chains running parallel to the a axis by weak inter-molecular C-H?S hydrogen bonds. Centrosymmetrically related chains are further connected by ?-? stacking inter-actions, with a centroid-to-centroid distance of 3.795?(5)?Å.

SUBMITTER: Kulcsar M 

PROVIDER: S-EPMC2960680 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Bis(diphenyl-phospho-rothio-yl) tris-ulfide.

Kulcsar Monika M   Silvestru Anca A   Vonas Marius M  

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

In the title compound, C(24)H(20)P(2)S(5), the P atoms are arranged trans with respect to the S(3) group and the S=P-S-S systems have cisoid geometry, with an average S-P-S-S torsion angle of -56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (10)°. In the crystal structure, the mol-ecules are linked into chains running parallel to the a axis by weak inter-molecular C-H⋯S hydrogen bonds. Centrosymmetrically related chains are further connect  ...[more]

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