Unknown

Dataset Information

0

Catena-Poly[[aqua-(pyrazino[2,3-f][1,10]phenanthroline-?N,N)cobalt(II)]-?-pyrazine-2,3-dicarboxyl-ato-?NO:O].

ABSTRACT: In the title compound, [Co(C(6)H(2)N(2)O(4))(C(14)H(8)N(4))(H(2)O)](n), the Co atom is bonded to one N,N'-bidentate pyrazino[2,3-f][1,10]phenanthroline (Pyphen) ligand, one N,O-bidentate pyrazine-2,3-dicarboxyl-ate (PZDC) dianion and one water mol-ecule in a distorted octa-hedral mer-CoN(3)O(3) geometry. The Co(II) atoms are bridged by the PZDC dianions, forming an infinite one-dimensional chain running along the b axis. Adjacent chains pack together through ?-? stacking inter-actions [centroid-centroid separations = 3.498?(4) and 3.528?(4)?Å], and O-H?O and O-H?N hydrogen bonds involving the water mol-ecule complete the structure.

SUBMITTER: Xu ZL 

PROVIDER: S-EPMC2960716 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[aqua-(pyrazino[2,3-f][1,10]phenanthroline-κN,N)cobalt(II)]-μ-pyrazine-2,3-dicarboxyl-ato-κNO:O].

Xu Zhan-Lin ZL   Li Xiu-Ying XY   Che Guang-Bo GB   Lu Lu L   Xu Chun-Hui CH  

Acta crystallographica. Section E, Structure reports online 20080830 Pt 9

In the title compound, [Co(C(6)H(2)N(2)O(4))(C(14)H(8)N(4))(H(2)O)](n), the Co atom is bonded to one N,N'-bidentate pyrazino[2,3-f][1,10]phenanthroline (Pyphen) ligand, one N,O-bidentate pyrazine-2,3-dicarboxyl-ate (PZDC) dianion and one water mol-ecule in a distorted octa-hedral mer-CoN(3)O(3) geometry. The Co(II) atoms are bridged by the PZDC dianions, forming an infinite one-dimensional chain running along the b axis. Adjacent chains pack together through π-π stacking inter-actions [centroid-  ...[more]

Similar Datasets

Unknown catena-Poly[[[aqua-(pyrazino-[2,3-f][1,10]phenanthroline-?N,N)zinc(II)]-?-penta-nedioato] monohydrate].
| S-EPMC3011601 | biostudies-literature
Unknown catena-Poly[[[aqua-(1,10-phenanthroline-κN,N')cadmium(II)]-μ-pyridine-2,3-dicarboxyl-ato-κN,O:O,O] dihydrate].
| S-EPMC2959933 | biostudies-literature
Unknown catena-Poly[[[aqua-(1,10-phenanthroline-?²N,N')zinc]-?-acetyl-ene-dicarboxyl-ato-?²O¹:O²] monohydrate].
| S-EPMC3393169 | biostudies-literature
Unknown A new polymorph of catena-poly[[tri-aqua-cadmium(II)]-?(2)-pyrazine-2,3-dicarboxyl-ato].
| S-EPMC2977175 | biostudies-literature
Unknown catena-Poly[[[diaqua-iron(II)]-?-pyrazine-2,3-dicarboxyl-ato] dihydrate].
| S-EPMC2915058 | biostudies-literature
Unknown catena-Poly[[[(1,10-phenanthroline-κN,N')zinc]-μ-pyridine-2,3-dicarboxyl-ato-κN,O:O,O] monohydrate].
| S-EPMC3152098 | biostudies-literature
Unknown catena-Poly[[[triaqua-copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl-ato] monohydrate].
| S-EPMC2914943 | biostudies-literature
Unknown 2,3-Bis(furan-2-yl)pyrazino-[2,3-f][1,10]phenanthroline.
| S-EPMC3884288 | biostudies-literature
Unknown catena-Poly[[aqua-(1,10-phenanthroline)cadmium(II)]-μ-benzene-1,4-di-carboxyl-ato].
| S-EPMC2967922 | biostudies-literature
Unknown catena-Poly[[aqua-(1,10-phenanthroline)cobalt(II)]-?-4,4'-(propane-1,3-diyldi-oxy)dibenzoato].
| S-EPMC2970340 | biostudies-literature