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4-[(E)-Phenyl-imino-meth-yl]benzonitrile.

ABSTRACT: In the mol-ecule of the title compound, C(14)H(10)N(2), the two aromatic rings are oriented at a dihedral angle of 32.22 (6)°. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(10) dimers. A weak π-π inter-action between the cyanobenzene rings, with a centroid-centroid distance of 3.8447 (3) Å, further stabilizes the crystal structure. There is also a C-H⋯π inter-action between the aniline ring and a CH group of the cyanobenzene ring.

SUBMITTER: Kashmiri MA

PROVIDER: S-EPMC2961095 | biostudies-literature |

REPOSITORIES: biostudies-literature

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2-Methyl-6-[2-(trifluoro-meth-yl)phenyl-imino-meth-yl]phenol.

Project description:The title compound, C(15)H(12)F(3)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 38.79?(5)°. The mol-ecular structure is stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring. In addition, there is an intra-molecular short C-H?F contact.

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Project description:In the title compound, C(14)H(10)F(3)NO(2), the two benzene rings are oriented at a dihedral angle of 31.94?(14)°. An intra-molecular O-H?N hydrogen bond helps to stabilize the mol-ecular structure. In the crystal, inter-molecular O-H?O hydrogen bonding links the mol-ecules, forming chains running along the crystallographic a axis. The F atoms of the trifluoro-methyl group are disordered over two positions with refined site occupancies of 0.488?(5) and 0.512?(5).

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