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4-[(E)-Phenyl-imino-meth-yl]benzonitrile.

ABSTRACT: In the mol-ecule of the title compound, C(14)H(10)N(2), the two aromatic rings are oriented at a dihedral angle of 32.22 (6)°. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(10) dimers. A weak π-π inter-action between the cyanobenzene rings, with a centroid-centroid distance of 3.8447 (3) Å, further stabilizes the crystal structure. There is also a C-H⋯π inter-action between the aniline ring and a CH group of the cyanobenzene ring.

SUBMITTER: Kashmiri MA

PROVIDER: S-EPMC2961095 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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4-[(E)-Phenyl-imino-meth-yl]benzonitrile.

Kashmiri Mmuhammad Akram MA Tahir M Nawaz MN Akhtar Muhammad M Ahmed Mushtaq M Hanif Ch Asif A

Acta crystallographica. Section E, Structure reports online 20080402 Pt 5

In the mol-ecule of the title compound, C(14)H(10)N(2), the two aromatic rings are oriented at a dihedral angle of 32.22 (6)°. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(10) dimers. A weak π-π inter-action between the cyanobenzene rings, with a centroid-centroid distance of 3.8447 (3) Å, further stabilizes the crystal structure. There is also a C-H⋯π inter-action between the aniline ring and a CH group of the cyanobenzene ring ...[more]

PMID: 21202283

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