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4-[(4-Amino-3-pyrid-yl)imino-meth-yl]benzonitrile.

ABSTRACT: The asymmetric unit of the potential mono-Schiff base ligand title compound, C(13)H(10)N(4), contains two crystallographically independent mol-ecules, A and B. In mol-ecule A, the two rings are twisted from each other by 13.90 (18)°. By contrast, the dihedral angle between the two rings in mol-ecule B is 0.67 (19)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯N inter-actions via R(4) (4)(32) motifs, forming two-dimensional arrays. The short distances between the centroids of the six-membered rings indicate the existence of π-π inter-actions [centroid-centroid distances = 3.6880 (17)-3.7466 (15) Å].

SUBMITTER: Fun HK

PROVIDER: S-EPMC2959807 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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4-[(4-Amino-3-pyrid-yl)imino-meth-yl]benzonitrile.

Fun Hoong-Kun HK Kargar Hadi H Kia Reza R

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

The asymmetric unit of the potential mono-Schiff base ligand title compound, C(13)H(10)N(4), contains two crystallographically independent mol-ecules, A and B. In mol-ecule A, the two rings are twisted from each other by 13.90 (18)°. By contrast, the dihedral angle between the two rings in mol-ecule B is 0.67 (19)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯N inter-actions via R(4) (4)(32) motifs, forming two-dimensional arrays. The short distances between the c ...[more]

PMID: 21581317

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