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5,6-Dichloro-2-(2-fluoro-phen-yl)iso-indoline-1,3-dione.

ABSTRACT: The crystal structure of the title compound, C(14)H(6)Cl(2)FNO(2), exhibits C-H?? and ?-? inter-actions, which generate C(3) chains in the [100] direction. The ?-? inter-action occurs between the aromatic rings of isoindoline units, with a centroid-centroid distance of 3.672?Å and an inter-planar separation of 3.528?Å. The isoindoline unit is planar and inclined at an angle of 58.63?(18)° to the substituent benzene ring. The F atom is disordered over two positions, with refined occupancies of 0.669?(3) and 0.331?(3).

SUBMITTER: Buyukgungor O

PROVIDER: S-EPMC2961116 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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5,6-Dichloro-2-(2-fluoro-phen-yl)iso-indoline-1,3-dione.

Büyükgüngör Orhan O Odabaşoğlu Mustafa M

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5

The crystal structure of the title compound, C(14)H(6)Cl(2)FNO(2), exhibits C-H⋯π and π-π inter-actions, which generate C(3) chains in the [100] direction. The π-π inter-action occurs between the aromatic rings of isoindoline units, with a centroid-centroid distance of 3.672 Å and an inter-planar separation of 3.528 Å. The isoindoline unit is planar and inclined at an angle of 58.63 (18)° to the substituent benzene ring. The F atom is disordered over two positions, with refined occupancies of 0. ...[more]

PMID: 21202366

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