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2-{2,4,6-Tris(bromo-meth-yl)-3,5-bis-[(1,3-dioxoisoindolin-2-yl)meth-yl]benz-yl}iso-indoline-1,3-dione toluene monosolvate.


ABSTRACT: In the title compound, C36H24Br3N3O6·C7H8, the toluene solvent mol-ecule is associated with the receptor mol-ecule via C-H?? bonding. The planes of the phthalimido groups are inclined at 77.0?(1), 63.0?(1) and 77.8?(1)° with respect to the benzene ring. The mol-ecular conformation is stabilized by C-H?O and C-H?Br hydrogen bonds. The crystal structure features non-classical hydrogen bonds of the C-H?N, C-H?O and C-H?Br type, leading to a three-dimensional cross-linking of molecules. The pattern of non-covalent inter-molecular bonding is completed by O?Br halogen bonds [3.306?(3)?Å], which link the receptor mol-ecules into infinite strands extending along the a-axis direction.

SUBMITTER: Koch N 

PROVIDER: S-EPMC3998546 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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2-{2,4,6-Tris(bromo-meth-yl)-3,5-bis-[(1,3-dioxoisoindolin-2-yl)meth-yl]benz-yl}iso-indoline-1,3-dione toluene monosolvate.

Koch Niklas N   Seichter Wilhelm W   Mazik Monika M  

Acta crystallographica. Section E, Structure reports online 20140305 Pt 4


In the title compound, C36H24Br3N3O6·C7H8, the toluene solvent mol-ecule is associated with the receptor mol-ecule via C-H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The mol-ecular conformation is stabilized by C-H⋯O and C-H⋯Br hydrogen bonds. The crystal structure features non-classical hydrogen bonds of the C-H⋯N, C-H⋯O and C-H⋯Br type, leading to a three-dimensional cross-linking of molecules. The pattern  ...[more]

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