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1-Methyl-3-phenyl-sulfonyl-2-piperidone.

ABSTRACT: The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl-sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol-ecules are connected into centrosymmetric dimers via C-H?O inter-actions and these associate into layers via C-H?O-S contacts. Further C-H?O inter-actions involving both the carbonyl and sulfonyl O atoms consolidate the crystal packing by providing connections between the layers.

SUBMITTER: Zukerman-Schpector J

PROVIDER: S-EPMC2961210 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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1-Methyl-3-phenyl-sulfonyl-2-piperidone.

Zukerman-Schpector Julio J Olivato Paulo R PR Cerqueira Carlos R CR Vinhato Elisângela E Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20080416 Pt 5

The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl-sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol-ecules are connected into centrosymmetric dimers via C-H⋯O inter-actions and these associate into layers via C-H⋯O-S contacts. Further C-H⋯O inter-actions involving both the carbonyl and sulfonyl O atoms consolidate the crystal packing by providing conne ...[more]

PMID: 21202324

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