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Aqua-bis(1H-imidazole-?N)bis-(4-methyl-benzoato-?O,O')cadmium(II).

ABSTRACT: In the title compound, [Cd(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Cd(II) atom is coordinated by four carboxyl-ate O atoms from two bidentate chelating 4-methyl-benzoate ligands, two N atoms from two imidazole ligands and one water mol-ecule in a distorted penta-gonal bipyramidal geometry. Inter-molecular O-H?O hydrogen bonds between the coordinated water mol-ecule and the carboxyl-ate O atoms of 4-methyl-benzoate lead to an infinite chain. These chains are further self-assembled into a two-dimensional layer through N-H?O hydrogen bonds between the imidazole ligands and carboxyl-ate groups. One of the imidazole ligands is disordered over two positions with site-occupancy factors of 0.737?(4) and 0.263?(4).

SUBMITTER: Song WD

PROVIDER: S-EPMC2961263 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Aqua-bis(1H-imidazole-κN)bis-(4-methyl-benzoato-κO,O')cadmium(II).

Song Wen-Dong WD Ji Li-Li LL Huang Xiang-Hu XH

Acta crystallographica. Section E, Structure reports online 20080426 Pt 5

In the title compound, [Cd(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Cd(II) atom is coordinated by four carboxyl-ate O atoms from two bidentate chelating 4-methyl-benzoate ligands, two N atoms from two imidazole ligands and one water mol-ecule in a distorted penta-gonal bipyramidal geometry. Inter-molecular O-H⋯O hydrogen bonds between the coordinated water mol-ecule and the carboxyl-ate O atoms of 4-methyl-benzoate lead to an infinite chain. These chains are further self-assembled into a t ...[more]

PMID: 21202242

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