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Aqua-bis-(1-methyl-1H-imidazole-?N)bis-(nitrato-?O)copper(II).

ABSTRACT: The title complex mol-ecule, [Cu(NO(3))(2)(C(4)H(6)N(2))(2)(H(2)O)], has crystallographically imposed twofold symmetry. The Cu(II) atom displays a distorted square-pyramidal CuN(2)O(3) coordination geometry. In the crystal, inter-molecular O-H?O hydrogen bonds between the coordinated water mol-ecule and the nitrate anions form chains parallel to the c axis.

SUBMITTER: Zhu RQ

PROVIDER: S-EPMC3011693 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Aqua-bis-(1-methyl-1H-imidazole-κN)bis-(nitrato-κO)copper(II).

Zhu Run-Qiang RQ

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

The title complex mol-ecule, [Cu(NO(3))(2)(C(4)H(6)N(2))(2)(H(2)O)], has crystallographically imposed twofold symmetry. The Cu(II) atom displays a distorted square-pyramidal CuN(2)O(3) coordination geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds between the coordinated water mol-ecule and the nitrate anions form chains parallel to the c axis. ...[more]

PMID: 21589302

Similar Datasets

[Aqua-bis-(nitrato-?O)copper(II)]-?-{bis-[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua-(nitrato-?O)copper(II)] nitrate monohydrate.

Project description:In the title binuclear complex, [Cu2(NO3)3(C18H16N6Se)(H2O)3]NO3·H2O, the Cu(II) ions are penta-coordinated in a tetra-gonal-pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water mol-ecule and a nitrate O atom, whereas the apical positions are occupied by a water mol-ecule for one Cu(II) ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C-Se-C plane. Numerous inter-molecular O-H?O and N-H?O hydrogen bonds between the coordinating and lattice water mol-ecules, nitrate anions and pyrazole groups are observed. ?-? stacking inter-actions between the pyridine rings [averaged centroid-centroid distance = 3.652?(5)?Å] are also present. The lattice water molecule is equally disordered over two sets of sites.

| S-EPMC3588734 | biostudies-literature

Aqua-bis(1H-imidazole-?N)bis-(4-methyl-benzoato-?O,O')cadmium(II).

Project description:In the title compound, [Cd(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Cd(II) atom is coordinated by four carboxyl-ate O atoms from two bidentate chelating 4-methyl-benzoate ligands, two N atoms from two imidazole ligands and one water mol-ecule in a distorted penta-gonal bipyramidal geometry. Inter-molecular O-H?O hydrogen bonds between the coordinated water mol-ecule and the carboxyl-ate O atoms of 4-methyl-benzoate lead to an infinite chain. These chains are further self-assembled into a two-dimensional layer through N-H?O hydrogen bonds between the imidazole ligands and carboxyl-ate groups. One of the imidazole ligands is disordered over two positions with site-occupancy factors of 0.737?(4) and 0.263?(4).

| S-EPMC2961263 | biostudies-literature

trans-Bis(nitrato-?O)tetra-kis-(1-vinyl-1H-imidazole-?N(3))copper(II).

Project description:In the title compound, [Cu(NO(3))(2)(C(5)H(6)N(2))(4)], the Cu(II) ion is located on an inversion centre. It features a Jahn-Teller-distorted octa-hedral coordination geometry, defined by four N atoms of four 1-vinyl-imidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801?(6):0.199?(6) ratio. In the crystal, the complex mol-ecules are linked by weak inter-molecular C-H?O and C-H?? inter-actions.

| S-EPMC3414114 | biostudies-literature

Tetra-aqua-bis-(2-methyl-1H-imidazole-?N)cobalt(II) naphthalene-1,5-disulfonate.

Project description:In the title complex, [Co(C(4)H(6)N(2))(2)(H(2)O)(4)](C(10)H(6)O(6)S(2)), the cation and anion both reside on crystallographic inversion centers, such that the asymmetric unit comprises one half cation and one half anion. The central Co(II) ion is coordinated by four water mol-ecules and two 2-methyl-imidazole ligands, resulting in a trans-octa-hedral coordination geometry. The existence of strong N-H?O and O-H?O hydrogen-bonding inter-actions gives rise to a three-dimensional structure.

| S-EPMC3238612 | biostudies-literature

Bis(2,2'-bi-1H-imidazole-?N,N)bis-(4-methyl-benzoato-?O)copper(II).

Project description:In title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(4))(2)], the Cu(II) atom (site symmetry ) is coordinated by two N,N'-bidentate 2,2'-biimidazole ligands and two weakly bonded 4-methyl-benzoate anions, resulting in a strongly elongated trans-CuO(2)N(4) octa-hedral geometry. In the crystal, adjacent mol-ecules are linked via pairs of N-H?O hydrogen bonds into chains propagating in [010].

| S-EPMC2972066 | biostudies-literature

Bis-(2-methyl-1H-imidazole-?N)bis[2-(naphthalen-2-yl)acetato-?O]copper(II).

Project description:In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)], the Cu(II) cations are square-planar coordinated by two 1-naphthyl-acetate anions and two 2-methyl-imidazole ligands into discrete complexes that are located on centres of inversion. These complexes are linked into chains parallel to [010] by inter-molecular N-H?O hydrogen bonding between the N-H H atom of the 2-methyl-imidazole ligands and the carboxyl-ate O atoms that are not involved in metal coordination.

| S-EPMC3238688 | biostudies-literature

catena-Poly[[[aqua-bis(1H-imidazole-?N)copper(II)]-?-naphthalene-1,4-dicarboxyl-ato-?O:O] dihydrate].

Project description:In the title compound, {[Cu(C(12)H(6)O(4))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation is coordinated by two naphthalene-1,4-dicarboxyl-ate (naph) dianions, two imidazole mol-ecules and one water mol-ecule in a distorted square-pyramidal geometry. The Cu-O bond distance in the apical direction is 0.509?(3)?Å longer than the mean Cu-O bond distance in the basal plane. The naph dianion bridges two Cu(II) cations, forming a one-dimensional polymeric chain. The coordinated water mol-ecule is hydrogen-bonded to the carboxylate groups and imidazole ligands of adjacent polymeric chains, forming a three-dimensional supra-molecular structure. No ?-? stacking is observed in the crystal structure. One solvent water molecule is disordered equally over two positions.

| S-EPMC2961746 | biostudies-literature

Bis(1-methyl-1H-imidazole-?N)bis-[2-(naphthalen-1-yl)acetato-?O]copper(II) monohydrate.

Project description:In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)]·H(2)O, the Cu(II) atom is coordinated by two 2-(naphthalen-1-yl)acetate anions and two 1-methyl-imidazole ligands, giving monomeric complexes with a square-planar coordination environment. Two complex mol-ecules and two water mol-ecules form a centrosymmetric ring system via O-H?O hydrogen bonds.

| S-EPMC3238723 | biostudies-literature

Di-chlorido-bis-[1-(2,4,6-tri-methyl-phen-yl)-1H-imidazole-?N (3)]copper(II).

Project description:In the title complex, [CuCl2(C12H14N2)2], the Cu(2+) cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle between the benzene ring of the mesityl moiety and the imidazole ring is 76.99?(18)°. Weak intra-molecular C-H?Cl hydrogen-bonding inter-actions consolidate the mol-ecular conformation.

| S-EPMC3884270 | biostudies-literature

Bis(imidazole-?N)bis-(nitrato-?O)zinc(II).

Project description:The title complex, [Zn(NO(3))(2)(C(3)H(4)N(2))(2)], contains a Zn(II) centre with a slightly distorted tetra-hedral coordination environment, involving two N atoms from imidazole ligands and two O atoms from nitrate anions. The imino NH groups participate in inter-molecular N-H?O hydrogen bonds.

| S-EPMC2970476 | biostudies-literature

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