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Tert-Butyl-dimethyl-silanol hemihydrate.

ABSTRACT: The crystal structure of the title compound, C(6)H(16)OSi·0.5H(2)O, reveals an asymmetric unit containing two mol-ecules of the silanol and a single water mol-ecule. There is evidence of hydrogen bonding between the three mol-ecules in the asymmetric unit. The H atoms of the silanol OH groups and the water H atoms are each disordered equally over two positions.

SUBMITTER: Barry SM

PROVIDER: S-EPMC2961358 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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tert-Butyl-dimethyl-silanol hemihydrate.

Barry Sarah M SM Mueller-Bunz Helge H Rutledge Peter J PJ

Acta crystallographica. Section E, Structure reports online 20080530 Pt 6

The crystal structure of the title compound, C(6)H(16)OSi·0.5H(2)O, reveals an asymmetric unit containing two mol-ecules of the silanol and a single water mol-ecule. There is evidence of hydrogen bonding between the three mol-ecules in the asymmetric unit. The H atoms of the silanol OH groups and the water H atoms are each disordered equally over two positions. ...[more]

PMID: 21202681

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