Browse
Submit Data
Databases
API
Help

Dataset Information

15 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris[4-chloro-2-(2-furylmethyl-imino-meth-yl)phenolato-?O,N]iron(III).

ABSTRACT: The title complex, [Fe(C(12)H(9)ClNO(2))(3)], is a mononuclear Schiff base iron(III) compound. The Fe atom is six-coordinated by three phenolic O and three imine N atoms from three Schiff base ligands in an octa-hedral geometry.

SUBMITTER: Feng MQ

PROVIDER: S-EPMC2961380 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Tris[4-chloro-2-(2-furylmethyl-imino-meth-yl)phenolato-κO,N]iron(III).

Feng Ming-Qian MQ Li Jing J Wei Wen-Jie WJ Liu Chang-Hong CH

Acta crystallographica. Section E, Structure reports online 20080517 Pt 6

The title complex, [Fe(C(12)H(9)ClNO(2))(3)], is a mononuclear Schiff base iron(III) compound. The Fe atom is six-coordinated by three phenolic O and three imine N atoms from three Schiff base ligands in an octa-hedral geometry. ...[more]

PMID: 21202498

Similar Datasets

Tris[2-(benzyl-imino-meth-yl)phenolato-?N,O]iron(III).

Project description:In the title compound, [Fe(C(14)H(12)NO)(3)], the Fe(III) atom has a slightly distorted octa-hedral geometry and is coordinated by three Schiff base ligands, viz. 2-(benzyl-imino-methyl)-phenolate. The crystal structure is stabilized by intra-molecular C-H?O and C-H?N hydrogen bonds.

| S-EPMC2960378 | biostudies-literature

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III).

Project description:The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.

| S-EPMC2961833 | biostudies-literature

Bis[(E)-4-chloro-2-(2-furylmethyl-imino-meth-yl)phenolato]iron(II).

Project description:The Fe atom of the title compound, [Fe(C(12)H(9)ClNO(2))(2)], lies on a crystallographic twofold rotation axis. The Fe(II) atom is four-coordinated in a tetra-hedral geometry by the O and N atoms of the two Schiff base ligands. The O atom of the furan substituent in the ligand unit is not involved in coordination to the Fe atom.

| S-EPMC2961607 | biostudies-other

Tris{2-[(furan-2-meth-yl)imino-meth-yl]-4-methyl-phenolato}cobalt(III).

Project description:In title compound, [Co(C(13)H(12)NO(2))(3)], the Co(III) ion is six-coordinated by three bidentate Schiff base ligands in a distorted octa-hedral environment. Adjacent complex mol-ecules are linked through C-H?O hydrogen bonds.

| S-EPMC3247556 | biostudies-literature

{4-Chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}{4-chloro-2-[(2-oxido-eth-yl)imino-meth-yl]phenolato}cobalt(III).

Project description:In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy-droxy and one oxide O atom from two Schiff base ligands, forming an octa-hedral geometry. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H?O hydrogen bonds. The 2-oxidoethyl group is disordered over two positions in a 0.638?(3):0.362?(3) ratio.

| S-EPMC3008055 | biostudies-literature

Tris[2-(propyl-imino-meth-yl)phenolato-?N,O]cobalt(III).

Project description:The title compound, [Co(C(10)H(12)NO)(3)], was synthesized from cobalt(III) fluoride and 2-(propyl-imino-meth-yl)phenol in refluxing methanol. The Co(III) ion is hexa-coordinated by three N and three O atoms from three bidentate Schiff base ligands in an octa-hedral geometry.

| S-EPMC2961544 | biostudies-literature

Bis[2-(butyl-imino-meth-yl)-4-chloro-phenolato]iron(II).

Project description:In the title compound, [Fe(C(11)H(13)ClNO)(2)], the Fe(II) atom is four-coordinated in a square-planar geometry by the O and N atoms of two 2-(butyl-imino-meth-yl)-4-chloro-phenolate Schiff base ligands.

| S-EPMC2961439 | biostudies-literature

Tris[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-?(2)N,O]cobalt(III).

Project description:The asymmetric unit of the title compound, [Co(C(9)H(8)Cl(2)NO)(3)], contains three independent mol-ecules. In each mol-ecule, the Co(III) ion is coordinated by an O atom and an N atom from three bidentate 2,4-dichloro-6-(ethyl-imino-meth-yl)phenolate ligands in a slightly distorted octa-hedral environment. In the crystal, a weak C-H?Cl hydrogen bond is observed.

| S-EPMC3414116 | biostudies-literature

Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-?(2) N,O]cobalt(III).

Project description:In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6?(2), 57.1?(2) and 62.9?(2)°. In the crystal, mol-ecules are linked by pairs of weak C-H?Br hydrogen bonds, forming inversion dimers.

| S-EPMC3884257 | biostudies-literature

Tris(2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolato-?(2)N,O(1))cobalt(III).

Project description:In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups. One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768?(5):0.232?(5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis. There are no classical hydrogen bonds in the structure, but C-H?? inter-actions occur.

| S-EPMC3379129 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data