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Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III).

ABSTRACT: The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.

SUBMITTER: Hao L

PROVIDER: S-EPMC2961833 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III).

Hao Lujiang L Mu Chunhua C Kong Binbin B

Acta crystallographica. Section E, Structure reports online 20080625 Pt 7

The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms. ...[more]

PMID: 21202804

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Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]cobalt(III).

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