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[6-(3,5-Dimethyl-1H-pyrazol-1-yl)picolinato](pyridine-2,6-dicarboxyl-ato)copper(II) dihydrate.

ABSTRACT: In the title complex, [Cu(C(7)H(4)NO(4))(C(11)H(10)N(3)O(2))]·2H(2)O, the Cu(II) atom is in a distorted octa-hedral geometry. The equatorial plane is formed by two N atoms and one O atom from 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate and by one N atom from pyridine-2,6-dicarboxyl-ate (pdc). Two pdc O atoms occupy the axial positions. Water mol-ecules are hydrogen bonded to the complex mol-ecules, forming a two-dimensional sheet structure.

SUBMITTER: Hu FL

PROVIDER: S-EPMC2961460 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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[6-(3,5-Dimethyl-1H-pyrazol-1-yl)picolinato](pyridine-2,6-dicarboxyl-ato)copper(II) dihydrate.

Hu Fei-Long FL Yin Xian-Hong XH Zhao Kai K Feng Yu Y Lin Cui-Wu CW

Acta crystallographica. Section E, Structure reports online 20080514 Pt 6

In the title complex, [Cu(C(7)H(4)NO(4))(C(11)H(10)N(3)O(2))]·2H(2)O, the Cu(II) atom is in a distorted octa-hedral geometry. The equatorial plane is formed by two N atoms and one O atom from 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate and by one N atom from pyridine-2,6-dicarboxyl-ate (pdc). Two pdc O atoms occupy the axial positions. Water mol-ecules are hydrogen bonded to the complex mol-ecules, forming a two-dimensional sheet structure. ...[more]

PMID: 21202496

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