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(S)-1-(2-Ammonio-3-methyl-butyl)-1,2-dihydro-pyridin-2-iminium dibromide.

ABSTRACT: In the title compound, C(10)H(19)N(3) (2+)·2Br(-), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80?(2)°]. The N atom of the ammonium group is displaced by 1.150?(8)?Å from the plane of these three C atoms. The iminium N atom lies on the opposite side of this plane. The crystal structure is stabilized by hydrogen bonds between the N and Br atoms, as well as by inter-molecular C-H?Br inter-actions.

SUBMITTER: Wang Y

PROVIDER: S-EPMC2961482 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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(S)-1-(2-Ammonio-3-methyl-butyl)-1,2-dihydro-pyridin-2-iminium dibromide.

Wang Yifeng Y Zhang Jixv J Chen Hui H Luo Shuping S

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

In the title compound, C(10)H(19)N(3) (2+)·2Br(-), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80 (2)°]. The N atom of the ammonium group is displaced by 1.150 (8) Å from the plane of these three C atoms. The iminium N atom lies on the opposite side of this plane. The crystal structure is stabilized by hydrogen bonds between the N and Br atoms, as well as by inter-molecular C-H⋯Br inter-actions. ...[more]

PMID: 21202549

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