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1,4,10,13-Tetra-oxa-7,16-diazo-niacyclo-octadecane bis-[tetra-chloridoaurate(III)] dihydrate.


ABSTRACT: The asymmetric unit of the title compound, (C(12)H(28)N(2)O(4))[AuCl(4)](2)·2H(2)O, contains one half-cation, one anion and one water mol-ecule; the cation is centrosymmetric. The Au ion has a square-planar coordination. In the crystal structure, intra-molecular N-H?O and O-H?O, and inter-molecular N-H?O, O-H?Cl and N-H?Cl hydrogen bonds link the ions and water mol-ecules, forming a supra-molecular structure.

SUBMITTER: Hojjat Kashani L 

PROVIDER: S-EPMC2961538 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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1,4,10,13-Tetra-oxa-7,16-diazo-niacyclo-octadecane bis-[tetra-chloridoaurate(III)] dihydrate.

Hojjat Kashani Leila L   Yousefi Mohammad M   Amani Vahid V   Khavasi Hamid Reza HR  

Acta crystallographica. Section E, Structure reports online 20080524 Pt 6


The asymmetric unit of the title compound, (C(12)H(28)N(2)O(4))[AuCl(4)](2)·2H(2)O, contains one half-cation, one anion and one water mol-ecule; the cation is centrosymmetric. The Au ion has a square-planar coordination. In the crystal structure, intra-molecular N-H⋯O and O-H⋯O, and inter-molecular N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds link the ions and water mol-ecules, forming a supra-molecular structure. ...[more]

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