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Bis[1,5-bis-(1H-indol-3-ylmethyl-ene)thio-carbazonato-?N,S]nickel(II) dimethyl sulfoxide disolvate.

ABSTRACT: The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The -CH=N-N=C(S)-NH-N=CH- frament is planar. The two indolyl -NH (donor) sites inter-act with dimethyl sulfoxide mol-ecules to furnish a layer motif.

SUBMITTER: Rizal MR

PROVIDER: S-EPMC2961539 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Bis[1,5-bis-(1H-indol-3-ylmethyl-ene)thio-carbazonato-κN,S]nickel(II) dimethyl sulfoxide disolvate.

Rizal Mohd Razali MR Ali Hapipah M HM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The -CH=N-N=C(S)-NH-N=CH- frament is planar. The two indolyl -NH (donor) sites inter-act with dimethyl sulfoxide mol-ecules to furnish a layer motif. ...[more]

PMID: 21202448

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