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Bis(acetone 4-phenyl-thio-semi-carbazonato-?N,S)zinc(II).


ABSTRACT: The Zn(II) atom in the title compound, [Zn(C(10)H(12)N(3)S)(2)], is N,S-chelated by the deprotonated Schiff base in a tetra-hedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N-H?? inter-action to an aromatic ring.

SUBMITTER: Tan KW 

PROVIDER: S-EPMC2977486 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Bis(acetone 4-phenyl-thio-semi-carbazonato-κN,S)zinc(II).

Tan Kong Wai KW   Ng Chew Hee CH   Maah Mohd Jamil MJ   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8


The Zn(II) atom in the title compound, [Zn(C(10)H(12)N(3)S)(2)], is N,S-chelated by the deprotonated Schiff base in a tetra-hedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N-H⋯π inter-action to an aromatic ring. ...[more]

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