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ABSTRACT:
SUBMITTER: Li XZ
PROVIDER: S-EPMC2961585 | biostudies-literature | 2008 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20080521 Pt 6
A new tetra-dentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenyl-butane-1,3-dione with (1S,2S)-(-)-1,2-diamino-cyclo-hexane. The chiral centers in the mol-ecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(-)-1,2-diamino-hexane. The cyclo-hexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclo-hexyl). The cr ...[more]