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Methyl 3-[(E)-furfuryl-idene]dithio-carbazate.

ABSTRACT: The mol-ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio-carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio-carbazate and furan units are located on opposite sides of the C=N double bond. The planar dithio-carbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2?(1)°. Adjacent mol-ecules are linked by N-H?S hydrogen bonding to form a supra-molecular dimer across an inversion center.

SUBMITTER: Shan S

PROVIDER: S-EPMC2961615 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Methyl 3-[(E)-furfuryl-idene]dithio-carbazate.

Shan Shang S Wang Shan-Heng SH Xu Ying-Li YL Xie Pei-Jin PJ Tian Yu-Liang YL

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

The mol-ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio-carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio-carbazate and furan units are located on opposite sides of the C=N double bond. The planar dithio-carbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2 (1)°. Adjacent mol-ecules are linked by N-H⋯S hydrogen bonding to form a supra-molecular dimer ...[more]

PMID: 21202699

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