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Methyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

ABSTRACT: In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inversion dimers via pairs of N-H⋯S hydrogen bonds involving the terminal S atom.

SUBMITTER: Tarafder MT

PROVIDER: S-EPMC3008995 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Methyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

Tarafder M T H MT Khan Sultana Shakila SS Islam M A A A A MA Lorenzi Lea L Zangrando Ennio E

Acta crystallographica. Section E, Structure reports online 20101020 Pt 11

In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inversion dimers via pairs of N-H⋯S hydrogen bonds involving the terminal S atom. ...[more]

PMID: 21589036

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Benzyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

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