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Methyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

ABSTRACT: In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inversion dimers via pairs of N-H⋯S hydrogen bonds involving the terminal S atom.

SUBMITTER: Tarafder MT

PROVIDER: S-EPMC3008995 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Benzyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

Project description:The title compound, C(17)H(16)N(2)S(2), a dithio-carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl-idine group. The 3-phenyl-prop-2-enyl-idene and dithio-carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074?(2)?Å, while the dihedral angle between the 3-phenyl-prop-2-enyl-idene and the benzyl group is 77.78?(7)°. In the crystal structure, mol-ecules are linked by an N-H?S hydrogen bond and a weak C-H?S inter-action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C-H?? inter-actions.

| S-EPMC2961473 | biostudies-literature

Methyl 3-[(E)-furfuryl-idene]dithio-carbazate.

Project description:The mol-ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio-carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio-carbazate and furan units are located on opposite sides of the C=N double bond. The planar dithio-carbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2?(1)°. Adjacent mol-ecules are linked by N-H?S hydrogen bonding to form a supra-molecular dimer across an inversion center.

| S-EPMC2961615 | biostudies-literature

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-?(2)N',S]mercury(II).

Project description:In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra-hedral coordination geometry best described as bis-phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro-gen and the thiol-ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75?(10)°. In the crystal, weak C-H?S inter-actions give rise to chains extending along the c axis.

| S-EPMC3393190 | biostudies-literature

Bis[benzyl 3-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-?(2)N(3),S]cadmium.

Project description:In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis-phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol-ate S atom. The dihedral angle between the two chelating ligands is 84.01?(9)°. Weak inter-molecular C-H?S inter-actions lead to the formation of chains along the c axis.

| S-EPMC3393227 | biostudies-literature

(E)-Methyl 3-(2-nitro-benzyl-idene)dithio-carbazate.

Project description:The asymmetric unit of the title compound, C(9)H(9)N(3)O(2)S(2), contains two independent mol-ecules, A and B, with similar bond dimensions. In both mol-ecules, the nitro group is tilted with respect to the aromatic ring [dihedral angles 32.0?(1)° in mol-ecule A and 34.0?(1)° in mol-ecule B]. The dithio-carbazate unit is nearly coplanar with the aromatic ring in both mol-ecules. For mol-ecule B, pairs of mol-ecules are linked by N-H?O and C-H?O hydrogen bonds about a centre of symmetry to form a dimer, whereas mol-ecules A are not involved in hydrogen bonding in the crystal structure.

| S-EPMC2915011 | biostudies-literature

Methyl 3-(2-hy-droxy-benzyl-idene)-2-methyl-dithio-carbazate.

Project description:In the title compound, C(10)H(12)N(2)OS(2), the thione and S-methyl groups are syn. An intra-molecular bifurcated O-H?(S,N) hydrogen bond occurs.

| S-EPMC3344635 | biostudies-literature

Benzyl 2-methyl-3-[(E)-(thio-phen-2-yl)methyl-idene]dithio-carbazate.

Project description:In the title compound, C(14)H(14)N(2)S(3), the thione S atom and methyl group are syn, as are the two thio-ether S atoms. The mol-ecule is twisted, the dihedral angles between the central (C(2)N(2)S(2)) residue and the pendent 2-thienyl and phenyl rings being 21.57?(6) and 77.54?(3)°, respectively. In the crystal, mol-ecules assemble into a three-dimensional architecture via C-H?? inter-actions, involving both the five- and six-membered rings as acceptors, as well as S?S inter-actions [3.3406?(5)?Å] between centrosymmetrically related 2-thienyl rings.

| S-EPMC3344150 | biostudies-literature

4-Eth-oxy-N-(3-phenyl-prop-2-enyl-idene)aniline.

Project description:The title compound, C(17)H(17)NO, was prepared by the condensation of cinnamaldehyde with p-phenetidine in ethanol. The prop-2-enyl-idene group exhibits an E configuration at the N=C and C=C double bonds, with C-N-C-C and C-C-C-C torsion angles of -179.9?(3) and -175.9?(3)°, respectively. The prop-2-enyl-idene group is not strictly planar [maximum deviation = 0.054?(4)?Å] and forms dihedral angles of 28.0?(3) and 34.9?(3)° with the attached aromatic rings.

| S-EPMC2961520 | biostudies-literature

N-[(E,Z)-1,3-Diphenyl-prop-2-enyl-idene]-N'-(1,3-dithio-lan-2-yl-idene)hydrazine.

Project description:Mol-ecules of the title compound, C(18)H(16)N(2)S(2), exist as the (2E, 1'Z)-isomer. The 1,3-dithiol-ane ring has an envelope conformation; the atoms of the C-C bond are disordered over two positions with occupancies of 0.47?(7) and 0.53?(7). The structure exhibits inter-molecular C-H?S and C-H??(arene) hydrogen bonds.

| S-EPMC2961686 | biostudies-literature

Methyl (E)-3-(2-bromo-4,5-dimeth-oxy-benzyl-idene)dithio-carbazate.

Project description:The title compound, C(11)H(13)BrN(2)O(2)S(2), was obtained from the condensation reaction of methyl dithio-carbazate and 2-bromo-4,5-dimeth-oxy-benzaldehyde. In the mol-ecule, the benzene ring and dithio-carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. The dithio-carbazate fragment is approximately planar (r.m.s deviation = 0.0281?Å) and the mean plane is oriented at a dihedral angle of 11.38?(15)° with respect to the benzene ring. In the crystal, pairs of N-H?S hydrogen bonds link the mol-ecules into centrosymmetric dimers.

| S-EPMC3247333 | biostudies-literature

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