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Rac-(1S,2R)-Diethyl 6-hydr-oxy-1-(4-methoxy-phen-yl)-3-oxo-2,3-di-hydro-1H-benzo[f]chromen-2-yl]-phospho-nate.

ABSTRACT: In the title compound, C(24)H(25)O(7)P, the ?-valerolactonyl ring exists in a distorted screw-boat conformation with the diethoxy-phosphoryl substituent occupying an axial position. The latter adopts an almost syn-periplanar conformation around the P-C bond. The mol-ecules form centrosymmetric dimers connected by O-H?O hydrogen bonds.

SUBMITTER: Wojciechowski J

PROVIDER: S-EPMC2961657 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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rac-(1S,2R)-Diethyl 6-hydr-oxy-1-(4-methoxy-phen-yl)-3-oxo-2,3-di-hydro-1H-benzo[f]chromen-2-yl]-phospho-nate.

Wojciechowski Jakub J Krawczyk Henryk H Albrecht Lukasz L Wolf Wojciech M WM

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the title compound, C(24)H(25)O(7)P, the δ-valerolactonyl ring exists in a distorted screw-boat conformation with the diethoxy-phosphoryl substituent occupying an axial position. The latter adopts an almost syn-periplanar conformation around the P-C bond. The mol-ecules form centrosymmetric dimers connected by O-H⋯O hydrogen bonds. ...[more]

PMID: 21202876

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