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Poly[{?(2)-1,2-bis-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]ethane}di-?(2)-cyanido-dicopper(I)].

ABSTRACT: The asymmetric unit of the title complex, [Cu(2)(CN)(2)(C(20)H(16)N(6)S(2))](n), contains one Cu(I) cation, one cyanide ligand and half of a centrosymmetric 1,2-bis-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]ethane (bppe) ligand. The Cu(I) atom displays a trigonal coordination geometry, being surrounded by one C atom from one cyanide anion and two N atoms from one cyanide and one bppe ligand. In the complex, each cyanide anion links two Cu(I) atoms in a bis-monodentate mode into a zigzag [-Cu-CN-](n) chain. Two parallel chains are linked by bppe ligands into a ladder chain.

SUBMITTER: Zhang YW

PROVIDER: S-EPMC2961664 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Poly[{μ(2)-1,2-bis-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]ethane}di-μ(2)-cyanido-dicopper(I)].

Zhang Ya-Wen YW Dong Hua-Ze HZ Cheng Lin L

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

The asymmetric unit of the title complex, [Cu(2)(CN)(2)(C(20)H(16)N(6)S(2))](n), contains one Cu(I) cation, one cyanide ligand and half of a centrosymmetric 1,2-bis-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]ethane (bppe) ligand. The Cu(I) atom displays a trigonal coordination geometry, being surrounded by one C atom from one cyanide anion and two N atoms from one cyanide and one bppe ligand. In the complex, each cyanide anion links two Cu(I) atoms in a bis-monodentate mode into a zigzag [-Cu-CN-](n ...[more]

PMID: 21202742

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