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Catena-Poly[[tris-(pyridine-?N)copper(II)]-?-tetra-fluoro-terephthalato-?O:O].


ABSTRACT: In the title compound, [Cu(C(8)F(4)O(4))(C(5)H(5)N)(3)](n), the Cu(II) atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra-fluoro-terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu(II) atoms are connected via the bridging tetra-fluoro-terephthalate ligands into a one-dimensional chain running along the [101] direction.

SUBMITTER: Zheng CG 

PROVIDER: S-EPMC2961727 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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catena-Poly[[tris-(pyridine-κN)copper(II)]-μ-tetra-fluoro-terephthalato-κO:O].

Zheng Chang-Ge CG   Zhang Jie J   Hong Jian-Quan JQ   Li Song S  

Acta crystallographica. Section E, Structure reports online 20080628 Pt 7


In the title compound, [Cu(C(8)F(4)O(4))(C(5)H(5)N)(3)](n), the Cu(II) atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra-fluoro-terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu(II) atoms are connected via the bridging tetra-fluoro-terephthalate ligands into a one-dimensional chain running along the [101] direction. ...[more]

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