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Catena-Poly[[bis-(methanol-?O)bis-(pyridine-?N)nickel(II)]-?-tetra-fluoro-terephthalato-?O:O'].

ABSTRACT: In the title compound, [Ni(C(8)F(4)O(4))(C(5)H(5)N)(2)(CH(4)O)(2)](n), the Ni(II) ion is located on an inversion center and is coordinated by four O atoms [Ni-O = 2.079?(4)?Å] from two tetra-fluoro-terephthalate ligands and two methanol mol-ecules, and by two N atoms [Ni-N = 2.127?(4)?Å] from two pyridine ligands in a distorted octa-hedral geometry. The Ni(II) ions are connected via the tetra-fluoro-terephthalate anions into a one-dimensional chain running along the crystallographic [011] direction.

SUBMITTER: Zheng CG

PROVIDER: S-EPMC2961662 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(methanol-κO)bis-(pyridine-κN)nickel(II)]-μ-tetra-fluoro-terephthalato-κO:O'].

Zheng Chang-Ge CG Hong Jian-Quan JQ Zhang Jie J Wang Chao C

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the title compound, [Ni(C(8)F(4)O(4))(C(5)H(5)N)(2)(CH(4)O)(2)](n), the Ni(II) ion is located on an inversion center and is coordinated by four O atoms [Ni-O = 2.079 (4) Å] from two tetra-fluoro-terephthalate ligands and two methanol mol-ecules, and by two N atoms [Ni-N = 2.127 (4) Å] from two pyridine ligands in a distorted octa-hedral geometry. The Ni(II) ions are connected via the tetra-fluoro-terephthalate anions into a one-dimensional chain running along the crystallographic [011] direct ...[more]

PMID: 21202750

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